Automated Disinfection System for Polyethylene Terephthalate Bottles for Bacteria, Fungi, and Viruses Using UVC LED Camera

The world is currently experiencing a crisis, caused by SARS-CoV-2 and a viral mutation. Given this, the mechatronic system is proposed that allows disinfecting contaminated surfaces. This device makes it possible to disinfect polyethylene terephthalate (PET) bottles by applying short-wave UVC rays from 200 to 280 nm, which generates a germicidal effect. The machine consists of a UVC chamber, transport, and a control system. For this, the methodology of the Association of German Engineers (VDI 2206) was used, taking into account the Inventor, TIA Portal, and Factory IO software, managing to develop the system whose light-emitting diodes inside the camera project type C ultraviolet light, camera protected by strips of plastic sheet (ABS) acrylonitrile butadiene styrene anti-ultraviolet light that blocks the projection wave up to 98% of the radiation;the recycled PET bottles are moved through a linear conveyor belt that supports a maximum weight of 200 kg, controlled by a control panel. Obtaining the results in this research focused on the design of the prototype, with a feasible structural system thanks to its maximum efficiency in the disinfection process. It is concluded that it is feasible to design a machine that projects ultraviolet rays to disinfect recycled PET bottles to eliminate viruses, parasites, fungi, and bacteria. © 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.

Disposable face masks release micro particles to the aqueous environment after simulating sunlight aging: Microplastics or non-microplastics?

This study focuses on characterizing microplastics and non-microplastics released from surgical masks (SMs), N95 masks (N95), KN95 masks (KN95), and children's masks (CMs) after simulating sunlight aging. Based on micro-Raman spectrum analysis, it was found that the dominant particles released from masks were non-microplastics (66.76–98.85%). Unfortunately, CMs released the most microplastics, which is 8.92 times more than SMs. The predominant size range of microplastics was 30–500 µm, and the main polymer types were PP and PET. Compared with the whole SMs, the microplastic particles released from the cutting-SMs increased conspicuously, which is 12.15 times that of the whole SMs. The main components of non-microplastics include β-carotene, microcrystalline cellulose 102, and eight types of minerals. Furthermore, non-microplastics were mainly fibrous and fragmented in appearance, similar to the morphology of microplastics. After 15 days of UVA-aging, the fibers of the face layers had cracks to varying degrees. It was estimated that these four types of masks can release at least 31.5 trillion microplastics annually in China. Overall, this study demonstrated that the masks could release a large quantity of microplastics and non-microplastics to the environment after sunlight aging, deserving urgent attention in the future study. © 2022 Elsevier B.V.

CO2-mediated thermal treatment of disposable plastic food containers

In accordance with global economic prosperity, the frequencies of food delivery and takeout orders have been increasing. The pandemic life, specifically arising from COVID-19, rapidly expanded the food delivery service. Thus, the massive generation of disposable plastic food containers has become significant environmental problems. Establishing a sustainable disposal platform for plastic packaging waste (PPW) of food delivery containers has intrigued particular interest. To comprise this grand challenge, a reliable thermal disposable platform has been suggested in this study. From the pyrolysis process, a heterogeneous plastic mixture of PPW was converted into syngas and value-added hydrocarbons (HCs). PPW collected from five different restaurants consisted of polypropylene (36.9 wt%), polyethylene (10.5 wt%), polyethylene terephthalate (18.1 wt%), polystyrene (13.5 wt%), polyvinyl chloride (4.2 wt%), and other composites (16.8 wt%). Due to these compositional complexities, pyrolysis of PPW led to formations of a variety of benzene derivatives and aliphatic HCs. Adapting multi-stage pyrolysis, the different chemicals were converted into industrial chemicals (benzene, toluene, styrene, etc.). To selectively convert HCs into syngas (H2 and CO), catalytic pyrolysis was adapted using supported Ni catalyst (5 wt% Ni/SiO2). Over Ni catalyst, H2 was produced as a main product due to C[sbnd]H bond scission of HCs. When CO2 was used as a co-reactant, HCs were further transformed to H2 and CO through the chemical reactions of CO2 with gas phase HCs. CO2-assisted catalytic pyrolysis also retarded catalyst deactivation inhibiting coke deposition on Ni catalyst. © 2022 Elsevier B.V.

From city to sea: Spatiotemporal dynamics of floating macrolitter in the Tiber River

Rivers are undoubtedly the main pathway of waste dispersed in the environment that from land reaches oceans and seas increasing the amount of marine litter. Major cities are a great source of riverine litter as large urbanization can originate pressure on the integrated waste management resulting in litter entering the rivers. Within this study, we aim to investigate the dynamic of floating riverine macrolitter (items >2.5 cm) in the city of Rome before it reaches the sea by assessing the composition, amount, and seasonal trends of litter transported from the urban centre to the main river mouth of Tiber River. Visual surveys for a whole year (March 2021–February 2022) were conducted from two bridges, Scienza Bridge (in the city) and Scafa Bridge (at the main river mouth) and followed JRC/RIMMEL protocol for riverine litter monitoring. Overall, similar litter composition was observed from the city centre to the mouth with a prevalence of plastic material, mainly related to fragmentation process (i.e. plastic pieces) and single use items, mainly in food and beverage sectors. An extrapolated annual loading of 4 × 105 items/year was estimated at the main mouth of Tiber River. The litter flux seems to be influenced by the seasonal variability and hydrometeorological parameters. The frequency of size classes decreases with increasing size in both sites, and more than half of the recorded items were below 10 cm. Specific categories belonging to "other plastics” have been reported related to anti-Covid-19 behaviour such as face masks and beverage sector, e.g. bottle lids and rings. The main colour of plastics was white, suggesting weathering process of floating riverine litter. This study contributes to increasing knowledge of the origin, composition and spatiotemporal dynamics of riverine floating litter from the city and entering the sea. © 2022 Elsevier B.V.

Survey of the European yarn fairs for autumn/winter 2023/24

The European yarn fairs for the autumn/winter 2023/24 season were held in a hesitant spirit, reflecting economic uncertainties affecting the whole of the textile and clothing industry. The industry has faced persistent disruptions to supply chains caused by lockdowns, which have continued to be imposed in major textile and clothing producing countries in an attempt to stem the spread of COVID-19. Furthermore, the war in Ukraine has introduced additional challenges—including difficulties in procuring raw materials and sharp increases in fuel and energy costs. At the same time, calls for the European textile and clothing industry to take action to reduce the damaging impact of its operations on the environment have intensified. It was evident at the fairs that many exhibitors had acknowledged these calls in the development of their product ranges for the autumn/winter 2023/24 season. Many had turned to using recycled waste materials in a bid to improve their sustainability credentials while some had implemented strategies aimed at reducing energy and water consumption and others had replaced materials derived from petroleum with natural materials. Several exhibitors had developed yarns made using materials derived from post-consumer waste polyethylene terephthalate (PET) plastic bottles. However, claims made about the environmental sustainability of such materials faced some challenges, given that synthetic fibres are known to be a cause of microplastics pollution. Yarns made from natural fibres, especially merino wool, were prevalent at the yarn fairs. However, there was a consensus among exhibitors that the industry is facing pressures to guarantee the welfare of the animals used in its supply chains. There was also a consensus that consumers are expecting manufacturers to be more responsible and transparent about the animal fibres they use. One of the ways in which manufacturers aim to meet these expectations in their product ranges for the autumn/winter 2023/24 season is to achieve compliance with international certification schemes, such as the Responsible Wool Standard (RWS). © Textiles Intelligence Limited 2022.

Biopolymeric sustainable materials and their emerging applications

Advancements in polymer science and engineering have helped the scientific community to shift its attention towards the use of environmentally benign materials for reducing the environmental impact of conventional synthetic plastics. Biopolymers are environmentally benign, chemically versatile, sustainable, biocompatible, biodegradable, inherently functional, and ecofriendly materials that exhibit tremendous potential for a wide range of applications including food, electronics, agriculture, textile, biomedical, and cosmetics. This review also inspires the researchers toward more consumption of biopolymer-based composite materials as an alternative to synthetic composite materials. Herein, an overview of the latest knowledge of different natural- and synthetic-based biodegradable polymers and their fiber-reinforced composites is presented. The review discusses different degradation mechanisms of biopolymer-based composites as well as their sustainability aspects. This review also elucidates current challenges, future opportunities, and emerging applications of biopolymeric sustainable composites in numerous engineering fields. Finally, this review proposes biopolymeric sustainable materials as a propitious solution to the contemporary environmental crisis. © 2022 Elsevier Ltd.

Quantification and mapping of domestic plastic waste using GIS/GPS approach at the city of Guayaquil

A significant contributor to the waste stream is the domestic single-use plastic used in households, being the final disposal in most cases the local landfill. There is a significant opportunity to promote resource recovery and efficiency through the introduction of circular economy strategies. However, the knowledge and management of post-consumer plastic waste in the country is poor, and there is a lack of an efficient collection and sorting system. In this context, spatial information on domestic plastic waste generation (DPWG) is essential for recycling decision-making. The integration of Geographic Information Systems (GIS) and the Global Positioning System (GPS) shows an opportunity to collect, mapping, and analyse spatial DPWG issues. Thus, this paper had a double objective. The first was to assess the evolution of eight different types of plastic waste in the city's households and their daily per capita generation between 2019 and 2021. The second objective was to provide a complete geo-referenced information on the quantities and typologies of domestic plastic waste (DPW) produced in Guayaquil and analyse how the flows have shifted throughout the years. The results showed that PET is the most generated, recording 97.76% and 100.00 % of the households who generate this type of plastic for 2019 and 2021, respectively, with an average of 13.08 and 15.13 g/day/c. Following, we had HDPE, PP and PVC occupying the second, third and fourth place for 2019 with 5.86, 3.05, 2.54 g/day/c, respectively. On the other hand, for 2021, PP (7.43 g/day/c), HDPE (5.92 g/day/c), and LDPE (3.99 g/day/c) occupied the second, third and fourth, respectively. According to the spatial maps, the DPW increment is in most of the popular zones. These popular zones are neighborhoods with a considerable quantity of population and limited basic services. Most of these people live in extreme poverty, being a possible relation between the COVID-19 lockdown and the increasement of DPW. © 2022 Elsevier B.V.. All rights reserved.